Synthesis of tin-encapsulated spherical hollow carbon for anode material in lithium secondary batteries.

نویسندگان

  • Kyu T Lee
  • Yoon S Jung
  • Seung M Oh
چکیده

The tributylphenyltin (TBPT)-encapsulated resorcinol (R)-formaldehyde (F) sol was prepared inside the micelles of cetyltrimethylammonium bromide (CTAB). This core-shell-type sol was polymerized and further carbonized to obtain nanosized Sn-encapsulated spherical hollow carbon. The size of spherical hollow carbon and Sn metal particles was controllable by changing the R/CTAB or TBPT/CTAB mole ratio, respectively. It is likely that, when tested as the anode in Li secondary batteries, the spherical hollow carbon acts as a barrier to prevent the aggregation of nanosized Sn particles and provides a void space for Sn metal particles to experience a volume change without a collapse of carbon shell, giving rise to a better cycle performance than that of pure Sn metal.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of Hard Carbon- Silicon Nanocomposite as Anode Active Material for Lithium-Ion Batteries

In this research, using phenolic resin as the precursor of carbon and various amounts of ethylene glycol as a pore former, porous samples of hard carbon were synthesized. Samples were characterized by x-ray diffraction (XRD) and N2 adsorption-desorption methods. Broad diffraction peaks represent the amorphous structure of samples. Moreover, the gas adsorption-desorption curves showed that the a...

متن کامل

Design and synthesis of micron-sized spherical aggregates composed of hollow Fe2O3 nanospheres for use in lithium-ion batteries.

A novel structure denoted a "hollow nanosphere aggregate" is synthesized by introducing nanoscale Kirkendall diffusion to the spray pyrolysis process. The hollow Fe2O3 nanosphere aggregates with spherical shape and micron size are synthesized as the first target material. A solid iron oxide-carbon composite powder that is prepared by a one-pot spray pyrolysis process is transformed into the hol...

متن کامل

Preparation of fluorine-doped, carbon-encapsulated hollow Fe3O4 spheres as an efficient anode material for Li-ion batteries.

Herein we report the design and synthesis of fluorine-doped, carbon-encapsulated hollow Fe3O4 spheres (h-Fe3O4@C/F) through mild heating of polyvinylidene fluoride (PVDF)-coated hollow Fe3O4 spheres. The spheres exhibit enhanced cyclic and rate performances. The as-prepared h-Fe3O4@C/F shows significantly improved electrochemical performance, with high reversible capacities of over 930 mA h g(-...

متن کامل

In situ synthesis of SnO2 nanoparticles encapsulated in micro/mesoporous carbon foam as a high-performance anode material for lithium ion batteries

State Key Laboratory of Silicon Materials, K Application for Batteries of Zhejiang Provin Engineering, Zhejiang University, Hangzhou edu.cn; Fax: +86 571 87951152; Tel: +86 57 Department of Chemical and Biomolecula College Park, MD 20742, USA. E-mail: cswa † Electronic supplementary information (TGA) prole of the SnO2@C porous com porous composite aer being ultrasoni galvanostatic charge–disc...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 125 19  شماره 

صفحات  -

تاریخ انتشار 2003